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2.two]decane core and defining the geometry of the exocyclic double bond. The activation energies of development on the vinyl-gold intermediates were calculated and uncovered a silyl enol ether with the unprotected indole moiety as a suitable precursor for that Toste cyclization. This six-step synthesis did not require any nonstrategic redox manipu
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2.two]decane core and defining the geometry of the exocyclic double bond. The activation energies of development from the vinyl-gold intermediates were being calculated and discovered a silyl enol ether with an unprotected indole moiety as a suitable precursor to the Toste cyclization. This six-action synthesis did not require any nonstrategic redo